Suppression of transition dipole moments in radioactive atoms

On shielding of nuclear electric dipole moments in atoms

We demonstrate explicitly that some recent calculations of atomic electric dipole moments (EDM) are incomplete. A contribution overlooked therein is pointed out. When included, it cancels exactly the result of those calculations, and thus restores the standard conclusions for nuclear EDM in atoms. The existence of EDMs of elementary particles, nuclei, and atoms is forbidden by CP invariance. Th...

Intrinsic electric dipole moments of paramagnetic atoms: rubidium and cesium.

The electric dipole moment (EDM) of paramagnetic atoms is sensitive to the intrinsic EDM contribution from that of its constituent electrons and a scalar-pseudoscalar (S-PS) electron-nucleus interaction. The electron EDM and the S-PS contributions to the EDMs of these atoms scale as approximately Z;{3}. Thus, the heavy paramagnetic atoms will exhibit large EDM enhancement factors. However, the ...

General magnetic transition dipole moments for electron paramagnetic resonance.

We present general expressions for the magnetic transition rates in electron paramagnetic resonance (EPR) experiments of anisotropic spin systems in the solid state. The expressions apply to general spin centers and arbitrary excitation geometry (Voigt, Faraday, and intermediate). They work for linear and circular polarized as well as unpolarized excitation, and for crystals and powders. The ex...

Transition from antibunching to bunching for two dipole-interacting atoms

It is known that there is a transition from photon antibunching to bunching in the resonance fluorescence of a driven system of two two-level atoms with dipole-dipole interaction when the atomic distance decreases and the other parameters are kept fixed. We give a simple explanation for the underlying mechanism which in principle can also be applied to other systems. PACS numbers 42.50.Ar, 42.50Fx

Ab initio dipole surfaces, vibrationally averaged dipole moments, and infrared transition intensities for KCN and LiCN